Helping people with computers... one answer at a time.
Windows 7 Professional and above include "Windows XP" mode. If you have programs that don't work or aren't available in Windows 7, XP Mode may help.
I'm hearing a lot of backlash against Windows 7 for a completely unexpected reason; not for incompatibilities or instabilities but for the removal of Outlook Express.
Outlook Express was actually removed in Windows Vista, being replaced by Windows Mail. That, in turn, was removed from Windows 7, and replaced with ... nothing. The official approach is to download Windows Live Mail, which is very Outlook Express-like.
But it's not Outlook Express.
It turns out that, yes, Windows XP Mode might be a solution.
It's not terribly simple, but it can work.
In fact, it can work for many programs that for one reason or another simply will not work in Windows 7, but used to work in Windows XP.
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Before I start, I do need to be clear: I'm not actually recommending this as an approach to using Outlook Express, specifically, in Windows 7. Not only is this somewhat cumbersome just to read email, but Outlook Express in general has enough problems that I'd strongly recommend moving away from it now. It just isn't worth this effort.
I show this in part for those diehards that must have Outlook Express at any cost, and as an example of the kinds of things that Windows XP Mode can be used for.
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Windows XP Mode is more than a "mode" - it installs an actual copy of Windows XP Professional as a virtual machine within Windows 7. That means you can run Windows XP within a window in Windows 7.

Within that copy of Windows XP you can run and use all your standard Windows XP programs, including Outlook Express:

Getting Windows XP Mode in Windows 7
Windows XP Mode is not included in the actual Windows 7 disks; it's a free download from Microsoft.
Windows XP Mode required Windows 7 Professional or better and a computer with a CPU capable of hardware assisted virtualization (the download page includes a tool that will tell you if you have this). I also recommend a huge chunk of disk space, and some patience - the download is over 500 megabytes.
Once downloaded the setup is actually very simple - the standard licensing term agreement and not even that many options or choices.

Once installed Windows XP Mode appears within All Programs -> Windows Virtual PC:

Run it and you'll find Windows XP running - in its own Window - on your machine running Windows 7.
I Have XP Mode, Now What?
Now that you're running Windows XP within a window, here's the simplest way to think of it:
Think of it as a separate machine running Windows XP. Treat it as a separate machine running Windows XP.
That means installing things like security updates, anti-malware software and whatever else you would do to a new machine that you'd just set up using Windows XP.
It also means that you can move your Outlook Express mail to this "new machine" and resume using Outlook Express.

The "C:" drive within a Windows XP virtual machine is a virtual hard drive that's stored as a single file as part of the virtual machine configuration. Naturally, that's where Windows XP stores its configuration, and your email, by default. I strongly recommend a good backup regimen within the virtual machine to back up your critical files - like your email - in a way that will not require the virtual PC of Windows XP Mode for recovery.
By default, Windows XP Mode also makes all the drives on your Windows 7 computer available from within the virtual PC:

As you can see above, all the drives on my Windows 7 machine - including any mounted volumes and local area network connections I might have - appear as folders accessible from within the Windows XP virtual machine, making data transfer in and out of the virtual machine a snap.
I've actually just scratched the surface on Windows XP Mode - Windows Virtual PC includes many features designed to make integration with legacy applications fairly easy. All we've really done above is setup a virtual machine, run it, and run one application within it.
All in all Windows XP Mode can be a very useful tool for overcoming compatibility issues, particularly with older software for which there may not be a Windows 7 alternative. While I don't actually recommend this approach for Outlook Express, the fact that it can be used shows just how much is possible. In effect, every copy of Windows 7 Professional or better includes this "free Windows XP" just for the downloading.
Article C3932 - November 21, 2009
Richard Joseph said (above)
> I haven't yet found any aspect of Outlook
> Express that isn't there in Windows Live Mail.
I haven't yet managed to find my Contacts/AddessBook
Posted by: Robin Clay at September 6, 2011 11:22 AMI know it's there, for I can add contacts to it, and am presented excerpts when I start to enter a name in the "To:" field.
But how to access it for inspection or edit - well, that's still a mystery to me.
But then, I am a novice - I've only been using computers since 1963...
Thank`s Leo,your solution solved the problem to my question,now i can use Xp within 7.
Posted by: Domingos Parreira at October 4, 2011 4:54 AMI am not able to use a HP printer connected to a PC running XP and shared from my laptop with Win7 because there are no drivers to support it. Can this be solved using the XP mode? Or are there any other suggestions to solve this?
Posted by: Freek at December 19, 2011 5:39 PMI am not able to use a HP printer connected to a PC running XP and shared from my laptop with Win7 because there are no drivers to support it. Can this be solved using the XP mode? Or are there any other suggestions to solve this?
Posted by: Freek at December 19, 2011 5:42 PM@Freek
Posted by: Mark J at December 20, 2011 12:05 AMSometimes a XP drivers will work in XP mode other times they won't. It's one thing you'll just have to try.